[en] We report on an unexpected lower critical solution temperature (LCST)-type phase transition of a poly(vinyl thiazolium) polymer in acetone solution, which was synthesized via radical polymerization of its corresponding ionic monomer bearing no thermoresponsiveness in acetone. The phase transition temperature can be conveniently varied by polymer concentration, ionic strength and addition of a cosolvent.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering Chemistry
Author, co-author :
Grygiel, Konrad; Max Planck Institute of Colloids and Interfaces, Department of Colloid Chemistry, Potsdam, Germany
Zhang, Weiyi; Max Planck Institute of Colloids and Interfaces, Department of Colloid Chemistry, Potsdam, Germany
Detrembleur, Christophe ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Yuan, Jiayin; Max Planck Institute of Colloids and Interfaces, Department of Colloid Chemistry, Potsdam, Germany
Language :
English
Title :
Unexpected LCST-type phase behaviour of a poly(vinyl thiazolium) polymer in acetone
Publication date :
2016
Journal title :
RSC Advances
eISSN :
2046-2069
Publisher :
Royal Society of Chemistry Publishing, Cambridge, United Kingdom
Volume :
6
Issue :
62
Pages :
57117-57121
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
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